Structural ( n, m) determination of isolated single-wall carbon nanotubes by resonant Raman scattering.

نویسندگان

  • A Jorio
  • R Saito
  • J H Hafner
  • C M Lieber
  • M Hunter
  • T McClure
  • G Dresselhaus
  • M S Dresselhaus
چکیده

We show that the Raman scattering technique can give complete structural information for one-dimensional systems, such as carbon nanotubes. Resonant confocal micro-Raman spectroscopy of an (n,m) individual single-wall nanotube makes it possible to assign its chirality uniquely by measuring one radial breathing mode frequency omega(RBM) and using the theory of resonant transitions. A unique chirality assignment can be made for both metallic and semiconducting nanotubes of diameter d(t), using the parameters gamma(0) = 2.9 eV and omega(RBM) = 248/d(t). For example, the strong RBM intensity observed at 156 cm(-1) for 785 nm laser excitation is assigned to the (13,10) metallic chiral nanotube on a Si/SiO2 surface.

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عنوان ژورنال:
  • Physical review letters

دوره 86 6  شماره 

صفحات  -

تاریخ انتشار 2001